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- W1520952634 abstract "In spite of the large number of reports on the physical properties of LiKSO4, its low-temperature phase diagram is still not well defined. One possible reason for this lack of reliable data below 100 K might be that LiKSO4 crystals often break into many pieces when cooled below 80 K under atmospheric pressure. We have found that it is possible to thermally cycle LiKSO4 crystals, particularly at temperatures below 80 K, as long as a minimum pressure of about 0.5 kbar is maintained. Thus, we successfully measured the temperature dependence of the sound velocity between 4 and 300 K for pressures up to 7 kbar. Over that temperature range, we clearly identify five different phase transitions (37, 48, 65, 185, 195 K) which correspond to those observed by other groups using different techniques. However, our results also show that both phase transitions below 50 K are strongly suppressed at pressures greater than 3 kbar. A Landau model of the free energy, based on the group theory, is also presented in order to explain the elastic and dielectric properties of LiKSO4 above 100 K. To support our analysis, we show how this model accounts for the temperature dependence of the strains, polarizations, dielectric susceptibility and elastic constants." @default.
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- W1520952634 date "2003-07-11" @default.
- W1520952634 modified "2023-09-27" @default.
- W1520952634 title "Investigation of the elastic properties of LiKSO<sub>4</sub>as a function of temperature and pressure" @default.
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- W1520952634 doi "https://doi.org/10.1088/0953-8984/15/29/309" @default.
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