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- W152112317 abstract "A large number of crystals whose states are described by an internal parameter are known. This parameter may characterize the distribution of the ions among inequivalent lattice positions (olivines, spinels, garnets, alloys, etc.) or among lattice points and interstices (superionic conductors), as well as the distribution of the electron density (cerium, chalcogenides, rare-earth elements). Phase transitions are possible in such systems. The internal parameter then serves as the order parameter. Thermodynamic models of the phase transformations have been proposed for each individual case. In this communication the authors propose a single model for describing the special features of the thermodynamic properties of the systems enumerated (and similar systems), and they have constructed possible phase diagrams." @default.
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- W152112317 date "1987-10-01" @default.
- W152112317 modified "2023-09-22" @default.
- W152112317 title "Thermodynamic description of phase transitions in crystals with an internal parameter" @default.
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