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- W1522751921 abstract "It is usually assumed that in α-ketoacids (R-CO-COO−), when the pH increases, the antecedent protonation occurs at the carboxylate group. A comparison of the cathode half-wave potentials and the ratio ΔE1/2/ΔpH as well as the determination of Taft's polar substituents δCOO−* and δCOOH* lead us to postulate that, in neutral media, the recorded recombination current corresponds to antecedent protonation of the carbonyl function. The antecedent protonation of the carboxylate group only occurs in a more acid medium (1<pH<5). The hydrate is not reducible because its protonation, followed by hydration, only occurs at the electrode at pH lower than 1." @default.
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- W1522751921 date "1977-08-01" @default.
- W1522751921 modified "2023-09-30" @default.
- W1522751921 title "Consequences of acceptor effects on the polarization of oxo and imine bonds in acyl and R-CO-COOH compounds" @default.
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- W1522751921 doi "https://doi.org/10.1016/s0022-0728(77)80033-8" @default.
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