Matches in SemOpenAlex for { <https://semopenalex.org/work/W1523184080> ?p ?o ?g. }
Showing items 1 to 99 of
99
with 100 items per page.
- W1523184080 endingPage "71" @default.
- W1523184080 startingPage "57" @default.
- W1523184080 abstract "Data obtained during cyclic and linear sweep voltammetry using current practice in peak potential measurements are somewhat qualitative, due to uncertainties in peak potential measurements and the lack of precise knowledge of the magnitude of uncompensated solution resistance. The precision problem is effectively eliminated by using derivative techniques and the IRu complication can be overcome by correlation of peak potential and peak current data. Linear correlations are suggested by the following equation: ΔEp=ΔErealp+IpRPu Correlation of the peak potential difference as a function of the peak current at constant Ru or as a function of Ru at constant Ip results in linear equations in which ΔErealp is derived from the intercepts. Both linear relationships were observed experimentally. Precise peak potential differences could be obtained for use in heterogeneous charge transfer kinetic studies. The method was applied to the quasi-reversible reduction of benzonitrile in DMF containing Bu4NBF4. The heterogeneous charge transfer rate constant was found to be 0.35±0.03 at 23.5°C at a supporting electrolyte concentration of 0.1 M." @default.
- W1523184080 created "2016-06-24" @default.
- W1523184080 creator A5034125673 @default.
- W1523184080 creator A5055692639 @default.
- W1523184080 date "1981-04-01" @default.
- W1523184080 modified "2023-10-14" @default.
- W1523184080 title "Quantitative cyclic voltammetry" @default.
- W1523184080 cites W1969900428 @default.
- W1523184080 cites W1970016844 @default.
- W1523184080 cites W1974268706 @default.
- W1523184080 cites W1974372621 @default.
- W1523184080 cites W1974529389 @default.
- W1523184080 cites W1993029321 @default.
- W1523184080 cites W2024497235 @default.
- W1523184080 cites W2040916647 @default.
- W1523184080 cites W2048178204 @default.
- W1523184080 cites W2072749499 @default.
- W1523184080 cites W2080870150 @default.
- W1523184080 cites W2093676012 @default.
- W1523184080 cites W2322164883 @default.
- W1523184080 cites W2950452300 @default.
- W1523184080 cites W2087858884 @default.
- W1523184080 doi "https://doi.org/10.1016/s0022-0728(81)80568-2" @default.
- W1523184080 hasPublicationYear "1981" @default.
- W1523184080 type Work @default.
- W1523184080 sameAs 1523184080 @default.
- W1523184080 citedByCount "33" @default.
- W1523184080 countsByYear W15231840802013 @default.
- W1523184080 countsByYear W15231840802015 @default.
- W1523184080 countsByYear W15231840802017 @default.
- W1523184080 crossrefType "journal-article" @default.
- W1523184080 hasAuthorship W1523184080A5034125673 @default.
- W1523184080 hasAuthorship W1523184080A5055692639 @default.
- W1523184080 hasConcept C100793964 @default.
- W1523184080 hasConcept C113196181 @default.
- W1523184080 hasConcept C121332964 @default.
- W1523184080 hasConcept C147789679 @default.
- W1523184080 hasConcept C148043351 @default.
- W1523184080 hasConcept C155647269 @default.
- W1523184080 hasConcept C17525397 @default.
- W1523184080 hasConcept C185592680 @default.
- W1523184080 hasConcept C188082385 @default.
- W1523184080 hasConcept C192562407 @default.
- W1523184080 hasConcept C199360897 @default.
- W1523184080 hasConcept C2777027219 @default.
- W1523184080 hasConcept C2777869211 @default.
- W1523184080 hasConcept C2778173763 @default.
- W1523184080 hasConcept C2779603750 @default.
- W1523184080 hasConcept C2779896888 @default.
- W1523184080 hasConcept C2779953769 @default.
- W1523184080 hasConcept C41008148 @default.
- W1523184080 hasConcept C43617362 @default.
- W1523184080 hasConcept C52859227 @default.
- W1523184080 hasConcept C62520636 @default.
- W1523184080 hasConcept C68801617 @default.
- W1523184080 hasConcept C97355855 @default.
- W1523184080 hasConceptScore W1523184080C100793964 @default.
- W1523184080 hasConceptScore W1523184080C113196181 @default.
- W1523184080 hasConceptScore W1523184080C121332964 @default.
- W1523184080 hasConceptScore W1523184080C147789679 @default.
- W1523184080 hasConceptScore W1523184080C148043351 @default.
- W1523184080 hasConceptScore W1523184080C155647269 @default.
- W1523184080 hasConceptScore W1523184080C17525397 @default.
- W1523184080 hasConceptScore W1523184080C185592680 @default.
- W1523184080 hasConceptScore W1523184080C188082385 @default.
- W1523184080 hasConceptScore W1523184080C192562407 @default.
- W1523184080 hasConceptScore W1523184080C199360897 @default.
- W1523184080 hasConceptScore W1523184080C2777027219 @default.
- W1523184080 hasConceptScore W1523184080C2777869211 @default.
- W1523184080 hasConceptScore W1523184080C2778173763 @default.
- W1523184080 hasConceptScore W1523184080C2779603750 @default.
- W1523184080 hasConceptScore W1523184080C2779896888 @default.
- W1523184080 hasConceptScore W1523184080C2779953769 @default.
- W1523184080 hasConceptScore W1523184080C41008148 @default.
- W1523184080 hasConceptScore W1523184080C43617362 @default.
- W1523184080 hasConceptScore W1523184080C52859227 @default.
- W1523184080 hasConceptScore W1523184080C62520636 @default.
- W1523184080 hasConceptScore W1523184080C68801617 @default.
- W1523184080 hasConceptScore W1523184080C97355855 @default.
- W1523184080 hasLocation W15231840801 @default.
- W1523184080 hasOpenAccess W1523184080 @default.
- W1523184080 hasPrimaryLocation W15231840801 @default.
- W1523184080 hasRelatedWork W1545576872 @default.
- W1523184080 hasRelatedWork W2000794888 @default.
- W1523184080 hasRelatedWork W2032018894 @default.
- W1523184080 hasRelatedWork W2035528449 @default.
- W1523184080 hasRelatedWork W2045569162 @default.
- W1523184080 hasRelatedWork W2091687853 @default.
- W1523184080 hasRelatedWork W2891529386 @default.
- W1523184080 hasRelatedWork W2954108992 @default.
- W1523184080 hasRelatedWork W3123156528 @default.
- W1523184080 hasRelatedWork W4235275459 @default.
- W1523184080 hasVolume "121" @default.
- W1523184080 isParatext "false" @default.
- W1523184080 isRetracted "false" @default.
- W1523184080 magId "1523184080" @default.
- W1523184080 workType "article" @default.