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- W1523348463 endingPage "846" @default.
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- W1523348463 abstract "Two successful synthetic routes to trichostatin A (1) are described; one (Scheme 2) uses the γ-alkylation of a silyl dienol ether, the other (Scheme 4) uses a silyl-protected cyanohydrin anion. The two routes bear an upolung relation to each other. The Lewis acid-catalysed acylation of silyl enol ethers is a simple and effective way to prepare β-diketones and β-keto esters (Scheme 1); this reaction however gave only ⇌-acylation of the silyl trienol ether (11) (Scheme 3), and the silyl trienol ether (11) had to be prepared by a round-about route (Scheme 3)." @default.
- W1523348463 created "2016-06-24" @default.
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- W1523348463 date "1983-01-01" @default.
- W1523348463 modified "2023-10-09" @default.
- W1523348463 title "The total synthesis of (± )-trichostatin A" @default.
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- W1523348463 doi "https://doi.org/10.1016/s0040-4020(01)88581-1" @default.
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