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- W1523735544 abstract "ESR spectra of 11BS and 10BS molecules in their ground 2Σ+ states were measured while isolated in solid neon and argon matrices at 4°K. g tensors and hyperfine structure constants for interaction with 11B and 10B were determined. In neon the magnetic parameters for BS are g∥11=2.0016(1), g⊥=1.9942(1), A∥(11B)= 853.3(3) MHz, and A⊥ (11B)=766.7(3) MHz. Observation of weak ESR signals attributed to 33S hfs yields | A⊥ (33S)|=16 (2) MHz. The observed Δ g⊥ is in excellent accord with the magnitude and sign of the spin-doubling constant, γo, as derived from published gas phase optical data. A CNDO calculation of the ground state wavefunction for BS was made and used to compare calculated spin densities and g values with experimental values. A comparison of the chemical bonding in BS and BO is given." @default.
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- W1523735544 date "1972-10-15" @default.
- W1523735544 modified "2023-10-18" @default.
- W1523735544 title "ESR of the BS Molecule in Inert Matrices at 4°K" @default.
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- W1523735544 doi "https://doi.org/10.1063/1.1678768" @default.
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