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- W1523922014 abstract "When spiropentane is formed in the gas-phase through the addition of dideuteriomethylene to methylenecyclopropane, the enthalpy of reaction must be unsymmetrically distributed at the instant of reaction. Nonetheless, the methylenecyclobutane, which is a secondary product of rearrangement of the initially formed excited spiropentane, manifests a statistically random distribution of deuterium, consistent with rapid flow of vibrational energy through a molecule. The lower homologue of this reaction, the addition of dideuteriomethylene to allene, also leads to a product, methylenecyclopropane, in which deuterium is randomly distributed (in pairs). An attempt to extend the study to the higher homolog, vinylcyclopropane, failed to produce significant results since the product of further rearrangement was the symmetrical molecule, cyclohexene." @default.
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- W1523922014 date "1968-01-01" @default.
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- W1523922014 title "Symmetrical distribution of energy in initially unsymmetrically excited products" @default.
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- W1523922014 doi "https://doi.org/10.1016/s0040-4020(01)96800-0" @default.
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