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- W1524005783 abstract "Advanced oxidation processes (AOPs) for the degradation of recalcitrant wastewater are of interest due to field application potential. We attempted the treatment of caprolactam (CL) wastewater which is highly acidic (pH 3.1) with low biodegradability index, using AOPs viz. electrochemical oxidation (EO) and ozonation. EO experiments under recirculation batch mode (20 mL min−1) in a three-dimensional carbon bed reactor confirmed 18% chemical oxygen demand (COD) reduction. The first order rate constant for the EO of CL wastewater was estimated as 1.38 ± 0.15 × 10−2 min−1. The apparent Faradic efficiency and specific energy consumption were found to be 9.4% and 2.75 kWh kg−1 COD, respectively. Similarly, 27% COD and 26% total organic carbon were removed during 4-h ozonation. Various organic compounds present in the raw and ozone treated effluent have been identified using GC-MS; while many degraded partially, CL persisted even in 10-h reacted samples. Both EO and ozonation methods are insufficient for the degradation of highly non-biodegradable complex wastewater." @default.
- W1524005783 created "2016-06-24" @default.
- W1524005783 creator A5007809758 @default.
- W1524005783 creator A5044242906 @default.
- W1524005783 date "2013-11-06" @default.
- W1524005783 modified "2023-09-24" @default.
- W1524005783 title "Treatment of Recalcitrant Caprolactam Wastewater Using Electrooxidation and Ozonation" @default.
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- W1524005783 doi "https://doi.org/10.1002/clen.201300177" @default.
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