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- W1524011618 abstract "The stabilities of the silica hydrosols Ludox HS and Ludox AM have been studied as a function of pH in the presence of various concentrations of several hydrolyzable electrolytes. “Log electrolyte concentration-pH” domains are given for the HS sol in Al(NO3)3 and Al2(SO4)3 solutions and for the AM sol in Al(NO3)3 and La(NO3)3 solutions. The ion-exchange mechanism of destabilization, which was previously established for the coagulation of silica with nonhydrolyzable electrolytes and for La(NO3)3 at low pH, is shown to hold for Al(NO3)3 and Al2(SO4)3 along the coagulation boundaries at pH < 4.5 and [Al3+] < 3 × 10−2M. Unhydrolyzed, hydrated Al3+ is the coagulant under these conditions for both of the aluminum salts. The difference in the coagulation behavior of aluminum sulfate and aluminum nitrate could be explained quantitatively by considering the formation of AlSO4+. Electrophoretic mobilities, determined by the moving boundary technique, are presented for conditions close to the coagulation boundary. Very little correlation was observed between the c.c.c. and the mobility. At low concentrations the shapes of the coagulation boundaries are determined by depletion of the bulk cation concentration due to exchange. Under these conditions the critical amounts of cation exchange of Al3+ and Ca2+ necessary for the destabilization of Ludox HS were calculated from the c.c.c. at two different sol concentrations." @default.
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- W1524011618 date "1971-01-01" @default.
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- W1524011618 title "Stability of colloidal silica" @default.
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