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- W1524251152 abstract "用端氨基聚乳酸做引发剂,在DMF中引发Ne-苄氧羰基-L-赖氨酸酐（Lys（Z）-NCA）聚合,合成了端氨基聚（Ne-苄氧羰基-L-赖氨酸）-b-聚乳酸两嵌段共聚物.以端羧基聚乙二醇经NHS活化与端氨基聚（Ne-苄氧羰基-L-赖氨酸）-b-聚乳酸偶联,合成了聚（乳酸-b-Ne-苄氧羰基-L-赖氨酸-b-乙二醇）三嵌段聚合物.利用IR、1H-NMR、GPC和TEM对它们的结构、形态进行了表征,结果表明,所合成的分子量可控、分子量分布窄（Mw/Mn=1.07）的嵌段共聚物,酰化反应产率达70%以上.同时聚乙二醇和Ne-苄氧羰基-L-赖氨酸被引入到聚乳酸主链中,在聚合物侧链脱保护后有望改善聚乳酸的细胞亲和性。" @default.
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- W1524251152 date "2010-06-12" @default.
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- W1524251152 title "SYNTHESIS AND CHARACTERIZATION OF AMPHIPHILIC TRIBLOCK COPOLYMERS PEG-POLY(<I>N</I><SUP>ε</SUP>-CBZ-LYSINE)-POLY(LACTIC ACID)" @default.
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- W1524251152 doi "https://doi.org/10.3724/sp.j.1105.2010.09395" @default.
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