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- W1524991618 abstract "A new empirical adsorption equation which enables us to interpret quantitatively the chemical structure-surface activity relationship for a homologous series of amphiphiles was developed. The proposed empirical adsorption isotherm takes into account parameters that are related to the amphiphile molecule's structure in contrast to hitherto existing well-known adsorption isotherms. On the basis of this equation, the surface excess concentration,Γ, surface area per molecule,A, and standard free energy of adsorption, ΔGπo, for three series of nonionic amphiphiles of the CnH2n+1-W type, i.e., 2-n-alkyl-1,3-oxathiolanes (I), 2-n-alkyl-1,3-dioxolanes (II), and aliphatic alcohols (III), whereW is the 1,3-oxathiolane ring, 1,3-dioxolane ring, and hydroxy group, respectively, were discussed." @default.
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- W1524991618 date "1991-12-01" @default.
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- W1524991618 title "Chemical structure and surface activity" @default.
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- W1524991618 doi "https://doi.org/10.1016/0021-9797(91)90183-9" @default.
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