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- W1525408462 abstract "C60 fullerene is able to form a complex with γ-cyclodextrin (CD). The supramolecular structure of this complex involves the encapsulation of the C60 molecule inside two CD molecules. Under these conditions the reactivity of C60 with ozone becomes about 200 times slower in comparison to free uncomplexed C60 as shown from a comparison of the kinetic rate constants. This novel approach, which involves the encapsulation of the molecule to be protected inside opportune host molecules, can be considered as a new conceptual tool in the protection of molecules and polymeric substrates from ozone degradation. The relative kinetic rate constants at room temperature for the ozonation of pure C60 in CCl4 have been measured, both at constant C60 concentration (changing the ozone feeding rate) and at constant ozone feeding rate (changing the C60 concentration). Preliminary results suggest that C60 ozonation seems to conform to the kinetic law v=k[O3]/[C60]." @default.
- W1525408462 created "2016-06-24" @default.
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- W1525408462 date "2002-01-01" @default.
- W1525408462 modified "2023-09-23" @default.
- W1525408462 title "Encapsulation of C60 fullerene in γ-cyclodextrin: a new concept in the protection of organic substrates and polymers from ozone attack" @default.
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- W1525408462 doi "https://doi.org/10.1016/s0141-3910(02)00087-3" @default.
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