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- W1525490634 abstract "Abstract Me 3 Si-X reagents react to completion at 25°C in a short time to convert Ir(H) 2 FL 2 (L=P t Bu 2 Ph) to Ir(H) 2 XL 2 . This involves formation of Ir-O, Ir-N, Ir-I, Ir-S and Ir-C(sp) bonds. Products include some η 2 -X ligands such as carboxylate and acetamide, NHC(O)CH 3 . The acetamide is shown to be η 2 in the solid state and in solution, but readily rearranges, by a transition state with Ir-O bond cleavage, to effect site exchange of the two inequivalent hydrides. The same synthetic approach succeeds for the more crowded metallated species and these reactions arc shown to fail when F is replaced by Cl in the iridium reagent. Unsaturation at Ir is suggested to be central to the mechanism of these F/X transposition reactions." @default.
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- W1525490634 date "1998-04-01" @default.
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- W1525490634 title "Silyl reagents (Me3Si-X) efficiently transfer X to Ir(H)2F(PtBuP2Ph)2" @default.
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- W1525490634 doi "https://doi.org/10.1016/s0020-1693(97)05851-9" @default.
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