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- W1525608793 abstract "Extended Hückel MO calculations have been applied to a large number of compact close-packed bare clusters of rhodium in order to establish their bonding abilities. The results show that the number of cluster valence molecular orbitals (CVMOs) can be expressed in the form 6N + X, with N equal to the number of metals and X a variable depending upon the cluster geometry. The value of X (which ranges from 6 to 11) is very often equal to 7. We suggest that any compact close-packed cluster compound should have 6N + 7 CVMOs or a number very close to this, and this is the case for the few known actual examples." @default.
- W1525608793 created "2016-06-24" @default.
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- W1525608793 date "1980-09-01" @default.
- W1525608793 modified "2023-10-16" @default.
- W1525608793 title "The stoichiometries of high-nuclearity transition metal carbonyl cluster compounds" @default.
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- W1525608793 doi "https://doi.org/10.1016/s0022-328x(00)93569-1" @default.
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