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- W152574934 abstract "The crystal nucleation and growth taking place in glassy and/or amorphous states of solids are of technological importance for characterizing the kinetically controlled stability of the non-crystalline state and for fabricating glass-ceramics with desired properties (Strnad Z, Glass-ceramic materials. Elsevier, Amsterdam, 1986; Sestak J, Thermophysical properties of solids. Elsevier, Amsterdam, 1984). The real kinetics of the crystallization processes is fairly complicated, controlled by various factors of physical properties of glass (Sestak J, Mares JJ, Hubik P (eds), Glassy, amorphous and nanocrystalline materials. Springer, Dordrecht, 2011) and of physicochemistry of elemental kinetic processes. Enormous effort has been paid to formalize the fundamental kinetic theory for the complicated consecutive and/or concurrent processes of nucleation and growth. As one of the results, the overall kinetics of nucleation and growth was formalized as the well-known Johnson–Mehl–Avrami–Erofeyev–Kolgomorov (JMAEK) equation (Jacobs PWM, Tompkins FC, Classification and theory of solid reactions. In: Garner WE (ed) Chemistry of the solid state. Butterworth, London, 1955). The kinetic equation is widely applied for varieties of the solid-state transformation processes (Weinberg MC (ed), Ceramic transactions. Nucleation and crystallization in liquids and glasses, vol 30. The American Ceramic Society, Westerville, 1993; Galwey AK, Brown ME, Thermal decomposition of ionic solids. Elsevier, Amsterdam, 1999; Koga N, Tanaka H, A physic-geometric approach to the kinetics of solid-state reactions as exemplified by the thermal dehydration and decomposition of inorganic solids. Thermochim Acta 388:41–61, 2002). At the same time, the theoretical and practical validities of the application of JMAEK transformation kinetics to the respective processes are always open to discussion (Finney EE, Finke RG, Is there a minimal chemical mechanism underlying classical Avrami–Erofe’ev treatments of phase-transformation kinetic data? Chem Mater 21:4692–4705, 2009)." @default.
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- W152574934 date "2012-01-01" @default.
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- W152574934 title "Influence of Preliminary Nucleation on the Physicogeometric Kinetics of Glass Crystallization" @default.
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