Matches in SemOpenAlex for { <https://semopenalex.org/work/W1526088078> ?p ?o ?g. }
- W1526088078 endingPage "77" @default.
- W1526088078 startingPage "7" @default.
- W1526088078 abstract "Publisher Summary This chapter discusses the free-radical reactions of carbohydrates as studied by radiation techniques. Radiation techniques are powerful tools for the study of free-radical reactions both in solution and in the solid state. In aqueous solution, the γ-radiolysis of the solvent water gives rise to OH radicals, solvated electrons, and H atoms as reactive species. While solvated electrons react slowly with carbohydrate, OH radicals and H atoms react quite readily with them, the former at nearly diffusion-controlled rates. Carbohydrate radicals undergo a number of elimination reactions, the most ubiquitous of which is the elimination of water. The elimination of HOR from β-alkoxy-α-hydroxyalkyl radicals has been reported for a number of compounds and under different conditions. Only the base-catalyzed elimination has been studied kinetically and it has been shown that its kinetics very much resemble those of the water elimination. Concepts related to the radical reactions of selected-compounds in aqueous solution are explained in the chapter, along with a discussion on the Radical reactions in crystalline carbohydrates." @default.
- W1526088078 created "2016-06-24" @default.
- W1526088078 creator A5009103445 @default.
- W1526088078 date "1980-01-01" @default.
- W1526088078 modified "2023-10-02" @default.
- W1526088078 title "Free-Radical Reactions of Carbohydrates as Studied by Radiation Techniques" @default.
- W1526088078 cites W100132439 @default.
- W1526088078 cites W111034434 @default.
- W1526088078 cites W1526255239 @default.
- W1526088078 cites W1579327898 @default.
- W1526088078 cites W1581960721 @default.
- W1526088078 cites W1586320548 @default.
- W1526088078 cites W1599818278 @default.
- W1526088078 cites W1601192578 @default.
- W1526088078 cites W1607086499 @default.
- W1526088078 cites W1616901194 @default.
- W1526088078 cites W1734848 @default.
- W1526088078 cites W176777829 @default.
- W1526088078 cites W1781537754 @default.
- W1526088078 cites W184192874 @default.
- W1526088078 cites W1842317625 @default.
- W1526088078 cites W1963711762 @default.
- W1526088078 cites W1966042924 @default.
- W1526088078 cites W1966114527 @default.
- W1526088078 cites W1966359810 @default.
- W1526088078 cites W1966660315 @default.
- W1526088078 cites W1969738045 @default.
- W1526088078 cites W1970094723 @default.
- W1526088078 cites W1970191866 @default.
- W1526088078 cites W1970230243 @default.
- W1526088078 cites W1970951110 @default.
- W1526088078 cites W1971639141 @default.
- W1526088078 cites W1972121567 @default.
- W1526088078 cites W1972429303 @default.
- W1526088078 cites W1972628854 @default.
- W1526088078 cites W1973169361 @default.
- W1526088078 cites W1973169834 @default.
- W1526088078 cites W1974431700 @default.
- W1526088078 cites W1975500956 @default.
- W1526088078 cites W1976314529 @default.
- W1526088078 cites W1978025333 @default.
- W1526088078 cites W1978620936 @default.
- W1526088078 cites W1980436638 @default.
- W1526088078 cites W1980556110 @default.
- W1526088078 cites W1982046766 @default.
- W1526088078 cites W1982691695 @default.
- W1526088078 cites W1982713483 @default.
- W1526088078 cites W1982846952 @default.
- W1526088078 cites W1983256598 @default.
- W1526088078 cites W1983380410 @default.
- W1526088078 cites W1985394758 @default.
- W1526088078 cites W1986556260 @default.
- W1526088078 cites W1986969781 @default.
- W1526088078 cites W1987039678 @default.
- W1526088078 cites W1987448064 @default.
- W1526088078 cites W1988500559 @default.
- W1526088078 cites W1988789804 @default.
- W1526088078 cites W1989649341 @default.
- W1526088078 cites W1989676905 @default.
- W1526088078 cites W1991127707 @default.
- W1526088078 cites W199203742 @default.
- W1526088078 cites W1992444465 @default.
- W1526088078 cites W1992754234 @default.
- W1526088078 cites W1992811774 @default.
- W1526088078 cites W1992910621 @default.
- W1526088078 cites W1994044569 @default.
- W1526088078 cites W1995539445 @default.
- W1526088078 cites W1995861900 @default.
- W1526088078 cites W1995913170 @default.
- W1526088078 cites W1996142823 @default.
- W1526088078 cites W1997134309 @default.
- W1526088078 cites W1997867411 @default.
- W1526088078 cites W1997911709 @default.
- W1526088078 cites W1998553793 @default.
- W1526088078 cites W1998809330 @default.
- W1526088078 cites W1998848635 @default.
- W1526088078 cites W1999457190 @default.
- W1526088078 cites W1999672977 @default.
- W1526088078 cites W2000088972 @default.
- W1526088078 cites W2003266260 @default.
- W1526088078 cites W2003510070 @default.
- W1526088078 cites W2004125842 @default.
- W1526088078 cites W2004260887 @default.
- W1526088078 cites W2006300542 @default.
- W1526088078 cites W2008007599 @default.
- W1526088078 cites W2008391270 @default.
- W1526088078 cites W2008815944 @default.
- W1526088078 cites W2009577138 @default.
- W1526088078 cites W2009692814 @default.
- W1526088078 cites W2009765001 @default.
- W1526088078 cites W2009767807 @default.
- W1526088078 cites W2011042156 @default.
- W1526088078 cites W2011250755 @default.
- W1526088078 cites W2012870195 @default.
- W1526088078 cites W2012935601 @default.
- W1526088078 cites W2013543065 @default.
- W1526088078 cites W2014325078 @default.
- W1526088078 cites W2014721496 @default.