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- W1526152021 abstract "Reactions of tricarbonyl-π-cyclopentadienylalkylmolybdenum compounds with cyclohexyl isocyanide were carried out. Reaction of cyclohexyl isocyanide with the methylmolybdenum derivative resulted in carbonyl insertion, affording an acyl complex, π-C2H5Mo(CO)2(CNC6H11)COCH3. No reaction occurred with the cyano- or chloromethyl derivatives. On the other hand, treatment with several p-substituted benzyl derivatives gave the imino complex, π-C5H5Mo(CO)3[C(CH2C6H4X-p)=NC6H11] (X = Cl, H, OCH3), as a main product and a small amount of the acyl complex. The yield of the imino complex increased and that of the acyl complex decreased with the increase of electron-attracting power of the para-substituent. The mechanism of isocyanide insertion reaction is discussed." @default.
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- W1526152021 date "1970-10-01" @default.
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- W1526152021 title "Studies on interactions of isocyanides with transition metal complexes" @default.
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- W1526152021 doi "https://doi.org/10.1016/s0022-328x(00)84504-0" @default.
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