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- W1526720793 abstract "Abstract The gas chromatographic behaviour of tetradentate Schiff base chelates of Cu(II), Ni(II), Pd(II) and VO(IV) on fused-silica wall-coated open-tubular columns have been examined and compared to results obtained on packed columns. The fused-silica column, expectedly, produced significant improvements in peak shape, resolution and detection limits. For example, fluorinated chelates of Cu(II) and Ni(II) which have previously not been resolved on packed columns were completely separated on the capillary columns. Nonetheless, limitations due to the reactivity and stability of the chelates remained. Residual activity in the column and activity created by chelates previously introduced onto the column were also evident. These effects were minimized by careful selection of ligand, column and column conditions." @default.
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- W1526720793 date "1985-01-01" @default.
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- W1526720793 title "Applications of fused-silica wall-coated open-tubular columns" @default.
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