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• W1526958927 abstract "The synthesis and (co-)polymerization of 2-(4-(pyridin-4-yl)piperazine-1-carboxamido)ethyl methacrylate (1) was carried out yielding the catalytically active poly(methacryloyl-4-(dialkylamino)pyridine) derivatives (2), (3) and (4). In addition, the tertiary-amine-containing terpolymers poly(methacryloyl-4-(dialkylamino)pyridine-co-butyl methacrylate-co-2-(dimethylamino)ethyl methacrylate) (5a − 5c) were prepared. Furthermore, kinetic studies of the acylation of tert-butanol with acetic anhydride to form tert-butyl acetate were conducted to evaluate the catalytic activity of the (co-)polymers. It turned out that homopolymer 2 exhibited the best performance, followed by the terpolymers 5a − 5c. The influence of the neighboring groups in the catalytic cycle is discussed. © 2015 Society of Chemical Industry" @default.
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• W1526958927 date "2015-07-03" @default.
• W1526958927 modified "2023-10-14" @default.
• W1526958927 title "Polymethacrylates containing a 4-amino-pyridyl derivative covalently attached as effective catalysts in acylation chemistry: self-activation by neighboring group effects" @default.
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• W1526958927 doi "https://doi.org/10.1002/pi.4959" @default.
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