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- W1528291481 abstract "Over the past decade, ionic liquids (ILs) have received great deal of attention as possible “green” replacement for volatile organic solvent mainly due to their nonmeasurable vapor pressure and good dissolubility for other salts. [1-5] Reaction types successfully performed in ILs include Diels–Alder, [6] Friedel–Crafts, [7] olefin hydrogenation, [8] hydroformyla‐ tion, [9] , [10] oligomerization, [11] and Heck and Suzuki coupling reactions. [12] , [13] In addition to solvent, ILs may have multiple functions in catalytic reactions. They may act as catalyst, co-catalyst, support, or ligands for the catalytic process. [14] In particular, some “unexpected” effects have been observed in affecting the catalytic reaction pathway. For ex‐ ample, the cations/anions in ILs may be involved in the formation of the active species changing the reaction mechanism. [15] [20] Understanding the functions of ILs in the cata‐ lytic reaction is of critical importance for deliberately modifying existed reaction system and exploiting new types of synthetic route by using this “green” solvent." @default.
- W1528291481 created "2016-06-24" @default.
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- W1528291481 date "2013-01-23" @default.
- W1528291481 modified "2023-09-26" @default.
- W1528291481 title "Ionic Liquids: “Green” Solvent for Catalytic Oxidations with Hydrogen Peroxide" @default.
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- W1528291481 doi "https://doi.org/10.5772/51936" @default.
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