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- W1528854515 abstract "The oxidative dehydrogenation (ODH) of n-octane to produce octene at atmospheric pressure has been studied using an industrially supplied iron molybdate catalyst fromJohnson Matthey (JM). In situ X-ray diffraction studies revealed at temperatures ≥450 °C the catalyst undergoes a reductive phase transition when reacted with noctaneat 450 °C where the phase changes from Fe2(MoO4)3-MoO3 to FeMoO4-MoO2-Mo4O11. As a result, if the temperature is taken back below this point the catalyst does not revert to the original phase and therefore the same activity and selectivity cannot be achieved. Thus the system can be considered as two different catalysts: i)the oxidised phases at temperatures < 450 °C, Fe2(MoO4)3-MoO3, which is associated with the production of octene and COx, and ii) as the reduced phases at temperatures ≥" @default.
- W1528854515 created "2016-06-24" @default.
- W1528854515 creator A5067402971 @default.
- W1528854515 date "2014-01-01" @default.
- W1528854515 modified "2023-09-28" @default.
- W1528854515 title "Alkanes, alkenes and aromatics: the oxidative dehydrogenation of n-octane using iron molybdate catalysts" @default.
- W1528854515 hasPublicationYear "2014" @default.
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