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- W1529510323 abstract "Oxidation of hydrocarbons are required for functionalizing hydrocarbons to yield products that are either important in themselves or are intermediate en route to other chemicals. In fine chemicals, because of stringent ecological standards, more emphasis is given to oxidation by molecular oxygen or hydrogen peroxide in preference to nonenvironmental friendly metal oxides. The catalytic activity of transition metal ions has been reported to be low as such in homogeneous system, while an enhanced activity was observed when they were heterogenized by supporting on to a solid support. Research for viable polymer supported catalysts for laboratory and industrial oxidation reactions has received recent scientific interest. The main problem is the leaching of the metal ion from the surface of the support when it is immobilized by the use of the monodentate or nonchelating ligands. Catalytic activity of different heterogenized chelated metal complex catalysts for various hydrogenation reactions has been reported. Covalently attached polymer bound multidentate amines could be valuable starting material to synthesize polymer bound chelates and macrocycles. This chapter discusses the synthesizing of the polymer bound Ru (III) complexes, using 1,2-diaminopropane (DAP), as a ligand, and oxidation of cyclohexane under mild reaction conditions, using the catalysts. Polymer bound Ru(III)-DAP complexes were found to be stable up to 100°C. These catalysts were found to be effective for oxidation of cyclohexane under mild operating conditions. The rate of reaction was studied by varying different parameters and the order of reaction with respect to catalyst as well as substrate was found to be fractional for both the catalysts." @default.
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- W1529510323 date "1997-01-01" @default.
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- W1529510323 title "Oxidation of cyclohexane using polymer bound Ru(III) complexes as catalysts" @default.
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- W1529510323 doi "https://doi.org/10.1016/s0167-2991(97)81083-x" @default.
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