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- W1529522076 abstract "The incorporation of a complexing agent within a polyarcylamide gel column provides a general means of manipulating the selectivity of a capillary electrophoresis separation. As an example of this approach, chiral resolution of dansylated amino acids by high-performance capillary electrophoresis has been achieved by adding β-cyclodextrin within the gel matrix. A retention model has been developed which can be used for selectivity optimization. Various parameters, such as concentration of cyclodextrin, addition of methanol to the buffer, and temperature, have been examined in terms of their influence on retention and selectivity. From this study high-performance separations have been developed. Efficiencies as high as 100 000 plates in 15 cm have been achieved." @default.
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- W1529522076 date "1988-01-01" @default.
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- W1529522076 title "Use of complexing agents for selective separation in high-performance capillary electrophoresis" @default.
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- W1529522076 doi "https://doi.org/10.1016/s0021-9673(01)84564-7" @default.
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