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- W1530202852 abstract "Direct dimetalation of 1-methyl-2-(methylthio)benzene (1) gives the dilithiated species (2) in good yield, which can be used to introduce substituents into the thiomethyl and methyl groups. Species 2 can react also with a variety of dichlorosilanes and dichlorostannanes, and with sulphur chloride, to yield derivatives of 1,3-benzothiasilin, 1,3-benzothiastannin and 1,3-benzodithiin respectively. Reaction of 2 with tetrachlorosilane yields a spirocyclic silicon compound, while reaction with benzoyl chloride yields a derivative of 1-benzothiopyran." @default.
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- W1530202852 date "1989-04-01" @default.
- W1530202852 modified "2023-10-09" @default.
- W1530202852 title "Metalation reactions" @default.
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- W1530202852 doi "https://doi.org/10.1016/0022-328x(89)87310-3" @default.
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