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- W1530291256 abstract "N-benzyloxycarbonyl-l-homoglutamine was studied to answer the question whether or not there is any tendency for the dehydration of the δ-carboxamide group during activation and coupling. Only a minor conversion to nitrile by-products was found in the activation of the α-carboxyl group and formation of peptide bond with the help of dicyclohexylcarbodiimide. Addition of N-hydroxybenzotriazole to the reacting mixture eliminates the side chain dehydration reaction. The dehydration reaction is also overcome by protection of the side chain carboxamide with the benzyloxycarbonylcarbamoyl substituent." @default.
- W1530291256 created "2016-06-24" @default.
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- W1530291256 date "2009-01-12" @default.
- W1530291256 modified "2023-09-23" @default.
- W1530291256 title "Side reactions of monoaminodicarboxylic acids in peptide synthesis" @default.
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- W1530291256 doi "https://doi.org/10.1111/j.1399-3011.1988.tb00006.x" @default.
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