Matches in SemOpenAlex for { <https://semopenalex.org/work/W1530459044> ?p ?o ?g. }
- W1530459044 endingPage "705" @default.
- W1530459044 startingPage "696" @default.
- W1530459044 abstract "Abstract The synthesis, reactivity, and catalytic activity of Ru II complexes with different pyridine‐ and imidazole‐based P,N ligands are reported. The investigations reveal a strong influence of the N‐heterocycle and the steric demand of the phosphine groups on the stability of different isomers of [L 2 RuX 2 ] (L = P,N ligand; X = Cl, H). The imidazole‐based complex 5 with dicyclohexylphosphine groups was found to be the most active precatalyst for the acceptorless dehydrogenation of primary alcohols, whereas different phosphine groups at the imidazole ligand as well as pyridine‐based ligands caused a drop in catalytic activity. In the presence of a primary amine, imines are preferentially formed under these conditions. In summary, the investigations show that comparably small changes in the ligand moiety have a strong effect on the relative stability of stereoisomers for both hydride and chloride complexes, whereas isomerization of the kinetic reaction products was observed in some cases. The described changes in the ligand moiety most probably have a strong impact on the relative stabilities of isomeric intermediates as well and thus affect the catalytic activity of these complexes." @default.
- W1530459044 created "2016-06-24" @default.
- W1530459044 creator A5001689812 @default.
- W1530459044 creator A5009571822 @default.
- W1530459044 creator A5025153098 @default.
- W1530459044 creator A5026042916 @default.
- W1530459044 creator A5027256677 @default.
- W1530459044 creator A5075065557 @default.
- W1530459044 creator A5078076793 @default.
- W1530459044 creator A5079154098 @default.
- W1530459044 date "2015-01-19" @default.
- W1530459044 modified "2023-10-16" @default.
- W1530459044 title "Formation of Different Isomers of Phosphine–Imidazolyl and –Pyridyl Ruthenium(II) Complexes Affecting the Catalyst Activity in the Acceptorless Dehydrogenation of Alcohols" @default.
- W1530459044 cites W1486766106 @default.
- W1530459044 cites W1541130678 @default.
- W1530459044 cites W1967087933 @default.
- W1530459044 cites W1967856577 @default.
- W1530459044 cites W1972768193 @default.
- W1530459044 cites W1972957600 @default.
- W1530459044 cites W1980901019 @default.
- W1530459044 cites W1983107490 @default.
- W1530459044 cites W1983610761 @default.
- W1530459044 cites W1986190616 @default.
- W1530459044 cites W1988979976 @default.
- W1530459044 cites W1990064600 @default.
- W1530459044 cites W1997027171 @default.
- W1530459044 cites W1997877566 @default.
- W1530459044 cites W2004971257 @default.
- W1530459044 cites W2005213632 @default.
- W1530459044 cites W2005273553 @default.
- W1530459044 cites W2006261739 @default.
- W1530459044 cites W2007293872 @default.
- W1530459044 cites W2007754309 @default.
- W1530459044 cites W2009626516 @default.
- W1530459044 cites W2011762034 @default.
- W1530459044 cites W2018014134 @default.
- W1530459044 cites W2019302034 @default.
- W1530459044 cites W2020078456 @default.
- W1530459044 cites W2022671939 @default.
- W1530459044 cites W2028439616 @default.
- W1530459044 cites W2030600868 @default.
- W1530459044 cites W2033385316 @default.
- W1530459044 cites W2037906407 @default.
- W1530459044 cites W2039584058 @default.
- W1530459044 cites W2040079056 @default.
- W1530459044 cites W2045757382 @default.
- W1530459044 cites W2047475425 @default.
- W1530459044 cites W2048503721 @default.
- W1530459044 cites W2050592102 @default.
- W1530459044 cites W2057546744 @default.
- W1530459044 cites W2065386992 @default.
- W1530459044 cites W2066378708 @default.
- W1530459044 cites W2069137488 @default.
- W1530459044 cites W2070703795 @default.
- W1530459044 cites W2084616510 @default.
- W1530459044 cites W2090549185 @default.
- W1530459044 cites W2090574683 @default.
- W1530459044 cites W2092604437 @default.
- W1530459044 cites W2095480759 @default.
- W1530459044 cites W2096659942 @default.
- W1530459044 cites W2107988377 @default.
- W1530459044 cites W2115476655 @default.
- W1530459044 cites W2120968379 @default.
- W1530459044 cites W2121091156 @default.
- W1530459044 cites W2130206239 @default.
- W1530459044 cites W2131350133 @default.
- W1530459044 cites W2131973597 @default.
- W1530459044 cites W2144045212 @default.
- W1530459044 cites W2144850396 @default.
- W1530459044 cites W2159458318 @default.
- W1530459044 cites W2164755792 @default.
- W1530459044 cites W2167165309 @default.
- W1530459044 cites W2167728799 @default.
- W1530459044 cites W2170100713 @default.
- W1530459044 cites W2313327466 @default.
- W1530459044 cites W2314704228 @default.
- W1530459044 cites W2315570686 @default.
- W1530459044 cites W2316125765 @default.
- W1530459044 cites W2317433266 @default.
- W1530459044 cites W2319877806 @default.
- W1530459044 cites W2320108646 @default.
- W1530459044 cites W2323512885 @default.
- W1530459044 cites W2325277599 @default.
- W1530459044 cites W2328016480 @default.
- W1530459044 cites W2334107503 @default.
- W1530459044 cites W2951238012 @default.
- W1530459044 cites W2952537091 @default.
- W1530459044 cites W2952914889 @default.
- W1530459044 cites W1986172526 @default.
- W1530459044 doi "https://doi.org/10.1002/ejic.201402970" @default.
- W1530459044 hasPublicationYear "2015" @default.
- W1530459044 type Work @default.
- W1530459044 sameAs 1530459044 @default.
- W1530459044 citedByCount "12" @default.
- W1530459044 countsByYear W15304590442015 @default.
- W1530459044 countsByYear W15304590442016 @default.
- W1530459044 countsByYear W15304590442017 @default.
- W1530459044 countsByYear W15304590442020 @default.