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- W1531505475 abstract "The reactivity of Me3SnMn(CO)5, (CH2CHCH2)3SnMn(CO)5, Me3SnFeCp(CO)2, and Me2Sn[FeCp(CO)2]2 has been investigated with respect to iodine, organomercury chlorides, trialkyl- and triarylchlorosilane, inorganic chlorides (SiCl4, SnCl4, TiCl4, ZnCl2, HgCl2) and Mn2(CO)l0. Iodination proceeded with dominant metal-metal bond cleavage in all solvents used, as was the case in most of the subsequent reactions, with the exception of the triallyltin derivative where carbon—metal bond fission occurred. Me3SnFeCp(CO)2 reacted with MeHgCl in a 11 ratio in DMSO-d6 to give initially MeHgFeCp(CO)2 and Me3SnCl which subsequently gave Me4Sn, Me2Hg, Hg[FeCp(CO)2]2 and ClHgFeCp(CO)2. In contrast with the phenyl analogue, the intermediate MeHgFeCp(CO)2 was not stable enough to be isolated. Me2Sn[FeCp(CO)2]2 reacted similarly but secondary reactions yielded Me3SnCl and, using excess MeHgCl, Me2SnCl2. Reaction of Me3SnMn(CO)5 followed similar patterns but in this instance MeHgMn(CO)5 appeared much more stable than PhHgMn(CO)5. Pathways accounting for all the products are discussed. Evidence is also presented for a range of exchange reactions with a variety of inorganic and organometallic chlorides." @default.
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- W1531505475 date "1973-01-01" @default.
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- W1531505475 title "Reactivity of metal-metal bonds" @default.
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- W1531505475 doi "https://doi.org/10.1016/s0022-328x(00)81746-5" @default.
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