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- W1531576366 abstract "Abstract The kinetics and thermal decomposition of t-butyl-1-adamantane percarboxylate has been studied in n-heptane, benzene, and carbon tetrachloride. The data obtained agree with the concerted perester decomposition mechanism yielding initially 1-adamantyl, t-butoxy radicals and carbon dioxide. The 1-adamantyl radical easily abstract chlorine fron carbon tetrachloride yielding 1-chloroadamantane; it abstracts hydrogen from n-heptane yielding adamantane and adds to benzene, yielding 1-phenyl adamantane. The perester obtained is an active initiator of methylmethacrylate polymerization, it is three times as active as the benzoyl peroxide." @default.
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- W1531576366 date "1969-01-01" @default.
- W1531576366 modified "2023-09-26" @default.
- W1531576366 title "The peroxy derivatives of adamantane" @default.
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