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- W1531777579 abstract "The formation, reactivity, and cycloaddition behavior of neopentylsilenes towards suitable reaction partners is described. Especially 1,1-dichloro-2-neopentylsilene, Cl2SiCHCH2But (2) - easily obtained from vinyltrichlorosilane and LiBu' - is a useful building block for the synthesis of SiC four membered ring compounds. These can be converted into the isomeric Diels-Alder and retro ene products upon thermolysis reactions. The mode of the silenes cycloaddition reactions ([4+2] vs [2+2] addition) can be directed by either the substitution pattern at the SiC moiety, the choice of reaction partners or the conditions. Furthermore the products resulting from cycloaddition reactions open up a wide variety of following reactions, which possibly will lead to new organosilicon materials or pharmaceutical compounds." @default.
- W1531777579 created "2016-06-24" @default.
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- W1531777579 date "1993-11-25" @default.
- W1531777579 modified "2023-10-03" @default.
- W1531777579 title "Neopentylsilenes: Laboratory Curiosities or Useful Building Blocks for the Synthesis of Silaheterocycles ?" @default.
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- W1531777579 doi "https://doi.org/10.1002/9783527619931.ch27" @default.
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