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- W1532253269 abstract "A reaction sequence has been developed for preparing hydroazulenones suitable for total synthesis of pseudoguaiane sesquiterpenes (→1 →2 →4). The relative configuration of bicyclic ketone 2 at three chiral centers was established by its conversion to (±)-damsinic acid (3). Subsequently, the C-10 chiral center of 2 was inverted by employing temporary vinyl activation (2 →27 →4). Ketone 4 thus produced is a potential synthon for helenanolides, having the required configuration at carbons 1, 5 and 10 found in that class of sesquiterpene lactones." @default.
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- W1532253269 date "1980-01-01" @default.
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- W1532253269 title "Total synthesis of pseudoguaianes—I" @default.
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