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- W1532350984 abstract "Abstract A quantum-statistical theory of longitudinal magnetic relaxation is given which is close to a thermodynamic description but does not assume a set of relaxing partial energies. The theory is based on a continued-fraction expansion of the dynamic susceptibility of a general system. The convergents of the continued fraction, which are equivalent to the [ N, N ] Pade approximations, are used to describe the low-frequency behaviour of the dynamic susceptibility. The formal expansion is investigated from a physical point of view. It is found that under certain conditions the expansion has a thermodynamic interpretation and provides a definition of relaxing sub-systems. The parameters of the continued fraction depend on the total hamiltonian. They are simplified by a perturbational approach, which permits an application of the theory to concrete systems." @default.
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- W1532350984 date "1973-06-01" @default.
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- W1532350984 title "Theory of longitudinal magnetic relaxation" @default.
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- W1532350984 doi "https://doi.org/10.1016/0031-8914(73)90333-9" @default.
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