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• W1532576328 endingPage "6944" @default.
• W1532576328 startingPage "6935" @default.
• W1532576328 abstract "Abstract An improved method for the tert ‐butanesulfinylation of diacetone glucose with tert ‐butanesulfinyl chloride is reported. The method is based on a beneficial effect of catalytic DMAP, which enhances both the rate of the reaction and the enantioselectivity of the process to give ( R S )‐diastereomer 2 R S with a 94 % de and in quantitative yield. ( R S )‐DAG sulfinate ester 2 R S is an excellent intermediate for the synthesis of enantiopure tert ‐butyl sulfoxides. Grignard agents and organolithium reagents can displace smoothly the diacetone glucose moiety to give synthetically relevant enantiopure sulfoxides, including highly functionalized derivatives, in high yields and with high enantioselectivities. ( R S )‐DAG sulfinate ester 2 R S is also an excellent N ‐sulfinylating agent; simple addition of LiHMDS (lithium hexamethyldisilazide) in THF gives ( S S )‐ tert ‐butanesulfinamide, and N ‐ tert ‐butanesulfinylimines are then formed in a two‐step one‐pot manner. N ‐Alkylated tert ‐butanesulfinamides are formed by the condensation of 2 R S with lithium amides." @default.
• W1532576328 created "2016-06-24" @default.
• W1532576328 creator A5003579126 @default.
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• W1532576328 creator A5032710486 @default.
• W1532576328 creator A5067041688 @default.
• W1532576328 date "2014-09-16" @default.
• W1532576328 modified "2023-10-17" @default.
• W1532576328 title "DMAP-Catalysed Sulfinylation of Diacetone-<scp>D</scp>-Glucose: Improved Method for the Synthesis of Enantiopure<i>tert</i>-Butyl Sulfoxides and<i>tert</i>-Butanesulfinamides" @default.
• W1532576328 cites W1966654760 @default.
• W1532576328 cites W1971386792 @default.
• W1532576328 cites W1972167384 @default.
• W1532576328 cites W1979223267 @default.
• W1532576328 cites W1979658967 @default.
• W1532576328 cites W1980536982 @default.
• W1532576328 cites W1985996124 @default.
• W1532576328 cites W1989659770 @default.
• W1532576328 cites W1991071994 @default.
• W1532576328 cites W1991811873 @default.
• W1532576328 cites W1991998089 @default.
• W1532576328 cites W2001265126 @default.
• W1532576328 cites W2002325687 @default.
• W1532576328 cites W2003518713 @default.
• W1532576328 cites W2003671777 @default.
• W1532576328 cites W2006052022 @default.
• W1532576328 cites W2006603931 @default.
• W1532576328 cites W2009158551 @default.
• W1532576328 cites W2012297069 @default.
• W1532576328 cites W2013601794 @default.
• W1532576328 cites W2019037762 @default.
• W1532576328 cites W2019247000 @default.
• W1532576328 cites W2020324128 @default.
• W1532576328 cites W2033004698 @default.
• W1532576328 cites W2033776465 @default.
• W1532576328 cites W2035149824 @default.
• W1532576328 cites W2040273361 @default.
• W1532576328 cites W2043735345 @default.
• W1532576328 cites W2045070878 @default.
• W1532576328 cites W2045141274 @default.
• W1532576328 cites W2050888400 @default.
• W1532576328 cites W2052648794 @default.
• W1532576328 cites W2056209565 @default.
• W1532576328 cites W2057021852 @default.
• W1532576328 cites W2059457864 @default.
• W1532576328 cites W2065986590 @default.
• W1532576328 cites W2074856645 @default.
• W1532576328 cites W2075813623 @default.
• W1532576328 cites W2079681695 @default.
• W1532576328 cites W2080199836 @default.
• W1532576328 cites W2082471444 @default.
• W1532576328 cites W2082926347 @default.
• W1532576328 cites W2083238120 @default.
• W1532576328 cites W2085812129 @default.
• W1532576328 cites W2099430873 @default.
• W1532576328 cites W2106184145 @default.
• W1532576328 cites W2112413919 @default.
• W1532576328 cites W2115997206 @default.
• W1532576328 cites W2116644666 @default.
• W1532576328 cites W2117418354 @default.
• W1532576328 cites W2119007778 @default.
• W1532576328 cites W2121848795 @default.
• W1532576328 cites W2124538138 @default.
• W1532576328 cites W2129142949 @default.
• W1532576328 cites W2131146694 @default.
• W1532576328 cites W2138127073 @default.
• W1532576328 cites W2142560573 @default.
• W1532576328 cites W2142690624 @default.
• W1532576328 cites W2151145752 @default.
• W1532576328 cites W2152415423 @default.
• W1532576328 cites W2158192184 @default.
• W1532576328 cites W2164254519 @default.
• W1532576328 cites W2167426231 @default.
• W1532576328 cites W2168679251 @default.
• W1532576328 cites W2170288763 @default.
• W1532576328 cites W2180864153 @default.
• W1532576328 cites W2325390731 @default.
• W1532576328 cites W2552039874 @default.
• W1532576328 cites W2949410348 @default.
• W1532576328 cites W2949634703 @default.
• W1532576328 cites W2949827806 @default.
• W1532576328 cites W2950078710 @default.
• W1532576328 cites W2950529568 @default.
• W1532576328 cites W2951196674 @default.
• W1532576328 cites W2951334415 @default.
• W1532576328 cites W2952489795 @default.
• W1532576328 cites W2952790279 @default.
• W1532576328 cites W2953250122 @default.
• W1532576328 cites W4383337823 @default.
• W1532576328 doi "https://doi.org/10.1002/ejoc.201402673" @default.
• W1532576328 hasPublicationYear "2014" @default.
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