Matches in SemOpenAlex for { <https://semopenalex.org/work/W1533222244> ?p ?o ?g. }
- W1533222244 endingPage "730" @default.
- W1533222244 startingPage "725" @default.
- W1533222244 abstract "γ,δ-Diamino acid structural motifs are commonly found in bioactive molecules. We report a one-pot reaction for the synthesis of γ,δ-diimino esters with two adjacent chiral centers in enantiomerically pure form through diaza-Cope rearrangement reaction of diimines formed from (R,R)-1,2-bis(2-hydroxyphenyl)-1,2-diaminoethane (hpen) and aldehydes. DFT computation provides interesting insights into the stereospecific rearrangement reaction. The crystal structure of a product diimine formed from the reaction of (R,R)-hpen and 2,6-dichlorobenzaldehyde shows that the reaction gives the product diimine in S,S configuration." @default.
- W1533222244 created "2016-06-24" @default.
- W1533222244 creator A5004073305 @default.
- W1533222244 creator A5008383067 @default.
- W1533222244 creator A5012929329 @default.
- W1533222244 creator A5040454396 @default.
- W1533222244 creator A5050049471 @default.
- W1533222244 creator A5077185233 @default.
- W1533222244 date "2013-11-28" @default.
- W1533222244 modified "2023-10-16" @default.
- W1533222244 title "Stereospecific Synthesis of γ,δ-Diamino Esters" @default.
- W1533222244 cites W1483512866 @default.
- W1533222244 cites W1523679951 @default.
- W1533222244 cites W1966592308 @default.
- W1533222244 cites W1967178061 @default.
- W1533222244 cites W1969921245 @default.
- W1533222244 cites W1971799292 @default.
- W1533222244 cites W1973801568 @default.
- W1533222244 cites W1978330900 @default.
- W1533222244 cites W1988044361 @default.
- W1533222244 cites W1991865146 @default.
- W1533222244 cites W1992115679 @default.
- W1533222244 cites W1997400930 @default.
- W1533222244 cites W2005018925 @default.
- W1533222244 cites W2008752896 @default.
- W1533222244 cites W2012909581 @default.
- W1533222244 cites W2016625343 @default.
- W1533222244 cites W2018200551 @default.
- W1533222244 cites W2028883188 @default.
- W1533222244 cites W2029225706 @default.
- W1533222244 cites W2031174235 @default.
- W1533222244 cites W2034877771 @default.
- W1533222244 cites W2036681077 @default.
- W1533222244 cites W2041753380 @default.
- W1533222244 cites W2046982629 @default.
- W1533222244 cites W2049417105 @default.
- W1533222244 cites W2051980016 @default.
- W1533222244 cites W2058719786 @default.
- W1533222244 cites W2064116691 @default.
- W1533222244 cites W2070423225 @default.
- W1533222244 cites W2078368610 @default.
- W1533222244 cites W2086035737 @default.
- W1533222244 cites W2087710238 @default.
- W1533222244 cites W2089399612 @default.
- W1533222244 cites W2092528857 @default.
- W1533222244 cites W2103561226 @default.
- W1533222244 cites W2104397822 @default.
- W1533222244 cites W2109574023 @default.
- W1533222244 cites W2121009566 @default.
- W1533222244 cites W2122230849 @default.
- W1533222244 cites W2128924487 @default.
- W1533222244 cites W2139841721 @default.
- W1533222244 cites W2164877636 @default.
- W1533222244 cites W2165637693 @default.
- W1533222244 cites W2167027103 @default.
- W1533222244 cites W2319561874 @default.
- W1533222244 cites W2321059743 @default.
- W1533222244 cites W2328461613 @default.
- W1533222244 cites W2328817785 @default.
- W1533222244 cites W2329449159 @default.
- W1533222244 cites W2335379339 @default.
- W1533222244 cites W2862766806 @default.
- W1533222244 cites W2949109597 @default.
- W1533222244 cites W2952863827 @default.
- W1533222244 cites W4235913504 @default.
- W1533222244 doi "https://doi.org/10.1002/ejoc.201301167" @default.
- W1533222244 hasPublicationYear "2013" @default.
- W1533222244 type Work @default.
- W1533222244 sameAs 1533222244 @default.
- W1533222244 citedByCount "9" @default.
- W1533222244 countsByYear W15332222442014 @default.
- W1533222244 countsByYear W15332222442016 @default.
- W1533222244 countsByYear W15332222442017 @default.
- W1533222244 countsByYear W15332222442018 @default.
- W1533222244 crossrefType "journal-article" @default.
- W1533222244 hasAuthorship W1533222244A5004073305 @default.
- W1533222244 hasAuthorship W1533222244A5008383067 @default.
- W1533222244 hasAuthorship W1533222244A5012929329 @default.
- W1533222244 hasAuthorship W1533222244A5040454396 @default.
- W1533222244 hasAuthorship W1533222244A5050049471 @default.
- W1533222244 hasAuthorship W1533222244A5077185233 @default.
- W1533222244 hasConcept C115624301 @default.
- W1533222244 hasConcept C161790260 @default.
- W1533222244 hasConcept C178790620 @default.
- W1533222244 hasConcept C185592680 @default.
- W1533222244 hasConcept C187921627 @default.
- W1533222244 hasConcept C21951064 @default.
- W1533222244 hasConcept C2776303508 @default.
- W1533222244 hasConcept C2991944050 @default.
- W1533222244 hasConcept C32909587 @default.
- W1533222244 hasConcept C71240020 @default.
- W1533222244 hasConceptScore W1533222244C115624301 @default.
- W1533222244 hasConceptScore W1533222244C161790260 @default.
- W1533222244 hasConceptScore W1533222244C178790620 @default.
- W1533222244 hasConceptScore W1533222244C185592680 @default.
- W1533222244 hasConceptScore W1533222244C187921627 @default.
- W1533222244 hasConceptScore W1533222244C21951064 @default.
- W1533222244 hasConceptScore W1533222244C2776303508 @default.