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- W1534176885 abstract "At temperatures between 473 and 673 K and pressures between 2 and 10 MPa, synthesis gas can be converted toward methanol, fuel-methanol (a mixture of methanol and higher alcohols), or a mixture of hydrocarbons (Fischer-Tropsch synthesis), depending on the type of heterogeneous catalyst applied. The gas-liquid solubilities of the solutes carbon monoxide, carbon dioxide, hydrogen, water, ethane, propane, pentane, hexane, methanol, ethanol, 1-propanol, 1-butanol, 1-pentanol, and 1-hexanol in the solvents tetraethylene glycol, hexadecane, octacosane, 1-hexadecanol, and phenanthrene were measured as a function of temperature. The solutes are all reactants or products relevant for synthesis gas conversion into alcohols and/or hydrocarbons. The solvents are seen as potentially attractive for synthesis gas conversion via gas-slurry processes. Experimental conditions varied between 293 and 553 K and 0.06 and 5.5 MPa, covering typical process conditions for synthesis gas conversion. The total set of experimental results consists of 1,533 gas-liquid solubilities divided over 60 binary systems. As far as the authors know hardly any of the gas-liquid solubilities from this set have been reported previously in the literature. Where literature data are available, a comparison is made with their data. This comparison always shows an agreement within the calculated experimental errors with an average deviationmore » of 7.6% and a maximal deviation of 15.0%.« less" @default.
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- W1534176885 date "1994-10-01" @default.
- W1534176885 modified "2023-09-26" @default.
- W1534176885 title "Gas-Liquid Solubilities of Carbon Monoxide, Carbon Dioxide,Hydrogen, Water, 1-Alcohols (1 .ltoreq. n .ltoreq. 6), and n-Paraffins (2 .ltoreq. n .ltoreq. 6) in Hexadecane, Octacosane, 1-Hexadecanol, Phenanthrene, and Tetraethylene Glycol at Pressures up to 5.5 MPa and Temperatures from 293 to 553 K" @default.
- W1534176885 doi "https://doi.org/10.1021/je00016a004" @default.
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