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- W1534449158 abstract "Our interest in elements 105, eka-tantalum, and 104, eka-hafnium, led us to study the thermal chromatographic behavior of gamma-emitting isotopes of Hf, Nb and Ta produced by combarding suitable targets with heavy ions at the Oak Ridge Isochronous Cyclotron. Atoms recoiling from the target were collected, chemically processed, and separated on-line with gaseous bromide systems. A mixture of bromine and boron tribromide was shown to be effective as the brominating agent. The separation of the metallic bromides produced was carried out in open tubular columns made of nickel of glass. A possible technique is outlined for the detection of alpha-emitting isotopes, which are of great importance in the transactinide region. Nickel was found to be sufficiently chemically resistant to the brominating atmosphere to be useful as the material for the chamber and target backing." @default.
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- W1534449158 date "1975-01-01" @default.
- W1534449158 modified "2023-10-18" @default.
- W1534449158 title "Thermochromatography of bromides" @default.
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- W1534449158 doi "https://doi.org/10.1016/s0021-9673(00)83803-0" @default.
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