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- W1535176957 abstract "Zusammenfassung Oxidative decarbonylation of Cp(CO) 2 WCNEt 2 (Cp = η 5 -C 5 H 5 ) ( 1 ) with Br 2 to give Cp(Br) 2 (CO)WCNEt 2 ( 2 ) followed by reductive elimination of the bromide ligands in 2 by Na/Hg in the presence of a 2e-donor ligand L represents a convenient route to electron-rich diethylaminocarbyne complexes of the type Cp(CO)(L)WCNEt 2 . This is demonstrated by the synthesis of the isocyanide and phosphane complexes Cp(CO)(RNC)WCNEt 2 ( 3a , 3b ) ( a : R = Et; b : R = t Bu) and Cp(CO)(PR 3 )WCNEt 2 ( 3c , 3d ) ( c : R = Me; d : R = Ph)." @default.
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- W1535176957 date "1991-01-01" @default.
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- W1535176957 title "Übergangsmetall-Carbin-Komplexe" @default.
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- W1535176957 doi "https://doi.org/10.1016/0022-328x(91)86237-k" @default.
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