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- W1535207101 abstract "A theoretical model is presented for isotachophoretic migration in systems where both the leading and terminating electrolytes contain another common component (admixture) (e.g., a difficult to remove impurity). The effective mobility of the admixture is lower than that of the leading ion and higher than that of the terminating ion. The model system includes a further two samples. The mathematical simulation of the separation dynamics of this system was obtained by solution of basic physico-chemical laws. This facilitated a comprehensive formulation of the principles of the steady state and calculations of the parameters of all zones. Based on the theoretical model, a method for the determination of admixture concentrations in the leading and terminating electrolytes from isotachophoretic measurements and accurate determination of the limiting mobilities of the separated compounds from experimental data affected by the presence of the admixture are described." @default.
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- W1535207101 date "1993-10-01" @default.
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- W1535207101 title "Electromigration in systems with additives in background electrolytes" @default.
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- W1535207101 doi "https://doi.org/10.1016/0021-9673(93)83306-d" @default.
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