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- W1535623481 abstract "In gamma-ray induced polymerization of formaldehyde, the effects of solvent and the copolymerization with vinyl monomers were studied. The rate of polymerization was of first order with respect to the dose rate; with respect to monomer concentration it was of second order in methylene chloride and toluene, but of first order in diethyl ether. From these results, the gamma-ray induced polymerization of formaldehyde seems to proceed predominantly by an ionic mechanism in solutions. Results of copolymerization showed that the polymerization proceeds in methylene chloride and in toluene by a cationic, in diethyl ether by an anionic mechanism. Bei der durch Gamma-Strahlen induzierten Formaldehydpolymerisation wurden der Lösungsmitteleinfluß sowie die Copolymerisation mit Vinylmonomeren studiert. Die Polymerisationsgeschwindigkeit war 1. Ordnung in bezug auf die Dosisleistung; in bezug auf die Monomerkonzentration war sie 2. Ordnung in Methylenchlorid und Toluol, jedoch 1. Ordnung in Diäthyläther. Danach scheint die durch Gamma-Strahlen induzierte Formaldehydpolymerisation in Lösung vornehmlich nach einem ionischen Mechanismus abzulaufen. Ergebnisse der Copolymerisation zeigten, daß die Polymerisation in Methylenchlorid und in Toluol nach einem kationischen, in Diäthyläther nach einem anionischen Mechanismus abläuft." @default.
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- W1535623481 date "1964-01-01" @default.
- W1535623481 modified "2023-10-09" @default.
- W1535623481 doi "https://doi.org/10.1002/macp.1964.020760117" @default.
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