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• W1535703397 startingPage "2861" @default.
• W1535703397 abstract "As is well-known, the C2H proton of 1-ethyl-3-methylimidazolium tetrafluoroborate ([Emim]BF4 ) and 1-butyl-3-methylimidazolium tetrafluoroborate ([Bmim]BF4 ) has a strong ability to form hydrogen bonds. The purpose of this work is to evaluate the effect of the interactions of the C4H and C5H protons on the microstructure of [Emim]BF4 and [Bmim]BF4 with water by using 1 H NMR spectroscopy. The differences between the relative 1 H NMR chemical shifts of C2H, C4H, and C5H and between the interaction-energy parameters obtained from these chemical shifts are minor, thus suggesting that the interactions of C4H and C5H may have a considerable effect on the microstructure. To confirm this, the viscosities of the systems are estimated by using the interaction-energy parameters obtained from the 1 H NMR chemical shifts of the three studied aromatic protons and water, showing that the interactions of C4H and C5H also play an important role in the microstructure." @default.
• W1535703397 created "2016-06-24" @default.
• W1535703397 creator A5006794114 @default.
• W1535703397 creator A5081497939 @default.
• W1535703397 date "2015-07-24" @default.
• W1535703397 modified "2023-10-16" @default.
• W1535703397 title "The Effect of C4H and C5H on the Microstructure of Aqueous Solutions of 1-Alkyl-3-methylimidazolium Tetrafluoroborate Ionic Liquids" @default.
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• W1535703397 doi "https://doi.org/10.1002/cphc.201500381" @default.
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