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- W1536762958 abstract "A detailed thermodynamic analysis of the double layer at the interface, simple inorganic oxide-aqueous solution, is presented with special emphasis on the assumptions normally made in relating experimental observation to theoretical treatment. An experimental study of the adsorption of potential-determining ions (H+, OH−) at the rutile (TiO2)/solution interface is reported. The results obtained by potentiometric titration of suspensions of the oxide indicate that equilibration is a two-step process with the initial fast step yielding the desired information on the surface behavior of the system. The point of zero charge (pzc) for TiO2 at room temperature was observed to lie at pH 6.0, independently of its crystalline modification, but was lowered to below pH 4 by heat treatment of the oxide prior to adsorption measurement. The pzc was also observed to approach the neutral point (12 pKw) with increasing temperature in the temperature range, 25°C to 95°C. A thermodynamic consideration of the transfer of cationic and anionic potential-determining species from the aqueous solution to the surface at the pzc allowed the difference in the standard entropy of transfer to be estimated from this information. The entropy difference (∼2.0 cal/deg mole) for TiO2 is compared with the much larger difference of ∼42 cal/deg-mole obtained from more extensive measurements on AgI. The striking difference between the two double layer systems is to be sought in differences in the structure and composition of the interphasal region separating the bulk phases which, in turn, must be related to the variation in interaction of the polar solvent with the solids, TiO2 and AgI." @default.
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- W1536762958 date "1968-06-01" @default.
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- W1536762958 title "Adsorption at the rutile-solution interface" @default.
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- W1536762958 doi "https://doi.org/10.1016/0021-9797(68)90038-6" @default.
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