FRINK Linked Data Fragments server

Matches in SemOpenAlex for { <https://semopenalex.org/work/W1537155220> ?p ?o ?g. }

• W1537155220 endingPage "105" @default.
• W1537155220 startingPage "95" @default.
• W1537155220 abstract "FTIR studies of CO adsorption have been carried out on Cu supported on ZnO, Al2O3, and SiO2. The reducibility of Cu as well as the surface structures of the metallic Cu particles formed were found to differ on the various supports. The active state of copper was found to be metallic-like in all the systems. The relative ease of reduction of Cu and the specific methanol synthesis activity decrease according to: Cu/ZnO>Cu/Al2O3≫Cu/SiO2. Changes in the reduction potential of the gas result in reversible surface structural changes for Cu/ZnO but not for Cu/Al2O3 or Cu/SiO2. Under moderate reducing condition, the CO adsorption results suggest that the Cu crystals on ZnO expose predominantly (110) facets. Under more severe reducing conditions, significant changes in the CO adsorption were observed and these cannot solely be explained by changes in the relative distribution of Cu surface planes. Instead, the IR transmission and CO adsorption results suggest that the higher reducing potential will lead to an increased number of oxygen vacancies at the ZnO surface and increased spreading of the Cu crystallites. Moreover, the large downward shifts in the CO band observed under severe reduction conditions suggest migration of zinc onto the surface of the Cu particles resulting in the formation of a Cu–Zn surface alloy. The proposal is seen to be in accord with recent surface science and theoretical investigations. The tendency to form the Cu–Zn surface alloy depends critically on the reduction potential of the gas. It is suggested that the recent observations of dynamic changes in the structural and catalytic properties of methanol synthesis catalysts is influenced by reversible reaction involving formation and destruction of the surface alloy." @default.
• W1537155220 created "2016-06-24" @default.
• W1537155220 creator A5015738926 @default.
• W1537155220 creator A5034356760 @default.
• W1537155220 date "1999-05-06" @default.
• W1537155220 modified "2023-10-17" @default.
• W1537155220 title "FTIR studies of dynamic surface structural changes in Cu-based methanol synthesis catalysts" @default.
• W1537155220 cites W1430763899 @default.
• W1537155220 cites W1517198205 @default.
• W1537155220 cites W1974147116 @default.
• W1537155220 cites W1979008448 @default.
• W1537155220 cites W1982304240 @default.
• W1537155220 cites W1988918848 @default.
• W1537155220 cites W1990446066 @default.
• W1537155220 cites W1992883585 @default.
• W1537155220 cites W1997098699 @default.
• W1537155220 cites W2005897483 @default.
• W1537155220 cites W2011317069 @default.
• W1537155220 cites W2011507821 @default.
• W1537155220 cites W2016528335 @default.
• W1537155220 cites W2025276052 @default.
• W1537155220 cites W2028009023 @default.
• W1537155220 cites W2029443417 @default.
• W1537155220 cites W2033487617 @default.
• W1537155220 cites W2049591180 @default.
• W1537155220 cites W2061163063 @default.
• W1537155220 cites W2323185909 @default.
• W1537155220 cites W248073613 @default.
• W1537155220 doi "https://doi.org/10.1016/s1381-1169(98)00253-2" @default.
• W1537155220 hasPublicationYear "1999" @default.
• W1537155220 type Work @default.
• W1537155220 sameAs 1537155220 @default.
• W1537155220 citedByCount "126" @default.
• W1537155220 countsByYear W15371552202012 @default.
• W1537155220 countsByYear W15371552202013 @default.
• W1537155220 countsByYear W15371552202014 @default.
• W1537155220 countsByYear W15371552202015 @default.
• W1537155220 countsByYear W15371552202016 @default.
• W1537155220 countsByYear W15371552202017 @default.
• W1537155220 countsByYear W15371552202018 @default.
• W1537155220 countsByYear W15371552202019 @default.
• W1537155220 countsByYear W15371552202020 @default.
• W1537155220 countsByYear W15371552202021 @default.
• W1537155220 countsByYear W15371552202022 @default.
• W1537155220 countsByYear W15371552202023 @default.
• W1537155220 crossrefType "journal-article" @default.
• W1537155220 hasAuthorship W1537155220A5015738926 @default.
• W1537155220 hasAuthorship W1537155220A5034356760 @default.
• W1537155220 hasConcept C127413603 @default.
• W1537155220 hasConcept C137637335 @default.
• W1537155220 hasConcept C147789679 @default.
• W1537155220 hasConcept C150394285 @default.
• W1537155220 hasConcept C160892712 @default.
• W1537155220 hasConcept C161790260 @default.
• W1537155220 hasConcept C178790620 @default.
• W1537155220 hasConcept C179104552 @default.
• W1537155220 hasConcept C185592680 @default.
• W1537155220 hasConcept C191897082 @default.
• W1537155220 hasConcept C192562407 @default.
• W1537155220 hasConcept C2779607525 @default.
• W1537155220 hasConcept C2780026712 @default.
• W1537155220 hasConcept C42360764 @default.
• W1537155220 hasConcept C535196362 @default.
• W1537155220 hasConcept C544153396 @default.
• W1537155220 hasConcept C544778455 @default.
• W1537155220 hasConcept C55493867 @default.
• W1537155220 hasConceptScore W1537155220C127413603 @default.
• W1537155220 hasConceptScore W1537155220C137637335 @default.
• W1537155220 hasConceptScore W1537155220C147789679 @default.
• W1537155220 hasConceptScore W1537155220C150394285 @default.
• W1537155220 hasConceptScore W1537155220C160892712 @default.
• W1537155220 hasConceptScore W1537155220C161790260 @default.
• W1537155220 hasConceptScore W1537155220C178790620 @default.
• W1537155220 hasConceptScore W1537155220C179104552 @default.
• W1537155220 hasConceptScore W1537155220C185592680 @default.
• W1537155220 hasConceptScore W1537155220C191897082 @default.
• W1537155220 hasConceptScore W1537155220C192562407 @default.
• W1537155220 hasConceptScore W1537155220C2779607525 @default.
• W1537155220 hasConceptScore W1537155220C2780026712 @default.
• W1537155220 hasConceptScore W1537155220C42360764 @default.
• W1537155220 hasConceptScore W1537155220C535196362 @default.
• W1537155220 hasConceptScore W1537155220C544153396 @default.
• W1537155220 hasConceptScore W1537155220C544778455 @default.
• W1537155220 hasConceptScore W1537155220C55493867 @default.
• W1537155220 hasIssue "1-3" @default.
• W1537155220 hasLocation W15371552201 @default.
• W1537155220 hasOpenAccess W1537155220 @default.
• W1537155220 hasPrimaryLocation W15371552201 @default.
• W1537155220 hasRelatedWork W1632137160 @default.
• W1537155220 hasRelatedWork W1993098890 @default.
• W1537155220 hasRelatedWork W2007094274 @default.
• W1537155220 hasRelatedWork W2049757704 @default.
• W1537155220 hasRelatedWork W2070652985 @default.
• W1537155220 hasRelatedWork W2326185588 @default.
• W1537155220 hasRelatedWork W2355862987 @default.
• W1537155220 hasRelatedWork W2402697569 @default.
• W1537155220 hasRelatedWork W2417131764 @default.
• W1537155220 hasRelatedWork W2469850045 @default.

• next