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- W1537488512 abstract "Stability of phases existing in chemical systems is determined by its Gibbs free energy designated as G. The relative position of Gibbs free energy surfaces in the G–T–X (composition) space determines stability ranges of respective phases yielding a map called the phase diagram. Since the knowledge of phase equilibria is essential in designing new materials, determination of Gibbs free energy for respective phases is being continued on both theoretical as well as experimental ways. While in principle chemical potentials of pure substances are needed to derive Gibbs free energy of formation of the stoichiometric phases, it is not the case for the phase ( solid or liquid) with variable composition. As an example, in Fig 1, Gm for three different systems is shown. Fig.1a shows free energy of formation of the intermetallic, stoichiometric Mg2Si phase recalculated per one mole of atoms (Turkdogan, 1980). Fig1b illustrates Gibbs energy of formation of one mole of liquid In-Pb solution (Hultgren, 1973). Finally, Fig.1c demonstrates Gibbs energy of formation of the solid phase, wustite ( ‘FeO’) (Spencer & Kubaschewski, 1978)." @default.
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- W1537488512 date "2011-11-21" @default.
- W1537488512 modified "2023-10-03" @default.
- W1537488512 title "Electromotive Force Measurements in High-Temperature Systems" @default.
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- W1537488512 doi "https://doi.org/10.5772/30231" @default.
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