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- W1538207911 abstract "In the fields of polymer and material chemistry, conjugated polymers (Skotheim et al., 2006) are an important class of polymers for next-generation optoelectronic materials due to their intriguing conductivity, photoluminescence, electroluminescence, and liquid crystallinity. Numerous conjugated polymers have been synthesized thus far, and a variety of unique conjugation systems have been incorporated into conjugated polymer backbones. One of the current research topics in this field focuses on the construction of layered and/or π-stacked structures. Layered π-electron systems are commonly found in both nature and artificial materials; for example, light-harvesting antenna complexes in photosynthetic systems, such as chlorophylls and bacteriochlorophylls, consist of layered π-electron systems. In optoelectronic materials, charges are delocalized in some layers and transferred from one electrode to the opposite one through the layered π-electron systems. Despite the importance of the layered structures of the π-electron systems, the synthesis of polymers comprising layered-aromatic rings and π-electron systems in a single polymer chain has rarely been studied (Morisaki & Chujo, 2006; Morisaki & Chujo, 2008a; Morisaki & Chujo, 2009d; Nakano, 2010). To achieve the construction of the desired layered structure, xanthene, anthracene, and naphthalene compounds can be employed as scaffolds. The rotary motion of two aromatic units substituted at the 4,5-positions of xanthene, 1,8-positions of anthracene, and 1,8positions of naphthalene is restricted due to steric hindrance, leading to a face-to-face structure. Thus, this review presents a summary of the syntheses and properties of a new class of aromatic ring-layered polymers, as well as oligomers containing xanthene, anthracene, and naphthalene scaffolds. Due to the vast number of studies on xanthene-, anthracene-, and naphthalene-based face-to-face dimeric systems, the polymers and oligomers (i.e., three or more face-to-face aromatic rings) are drawn." @default.
- W1538207911 created "2016-06-24" @default.
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- W1538207911 date "2011-09-26" @default.
- W1538207911 modified "2023-09-25" @default.
- W1538207911 title "Synthesis of Aromatic-Ring-Layered Polymers" @default.
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- W1538207911 doi "https://doi.org/10.5772/19353" @default.
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