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- W1539021515 abstract "Abstract A possibly general synthetic route to trialkylstannoxy compounds of the organotransition metal series was found, viz. the addition of hexamethyldistannane to trioxo(η 5 -pentamethylcyclopentadienyl)rhenium(VII) ( 1 ). The reaction occurs with concomitant cleavage of the tintin bond, and the air-sensitive product oxo(η 5 -pentamethylcyclopentadienyl)bis(trimethylstannoxy)rhenium(V) ( 2 ) was obtained in 90% yield after purification by recrystallisation from n-hexane/methylene chloride. The n-butyl derivative 2b (C 4 H 9 in place of CH 3 ) is prepared analogously." @default.
- W1539021515 created "2016-06-24" @default.
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- W1539021515 date "1989-02-01" @default.
- W1539021515 modified "2023-10-17" @default.
- W1539021515 title "Mehrfachbindungen zwischen Hauptgruppenelementen und Übergangsmetallen" @default.
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- W1539021515 doi "https://doi.org/10.1016/0022-328x(89)85299-4" @default.
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