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• W1539257349 abstract "The kinetics of the reaction of arylcyclopropanes (4-XC6H4C3H5, X = H, Me, EtO) with either [Pt2Cl2(μ-Cl)2(C2H4)2] or [{PtCl2(CH2CH2CH2)} in tetrahydrofuran to give in each case [{PtCl2(CHArCH2CH2)}4] and ethylene or cyclopropane, respectively, have been studied. The reactions are essentially first order in both arylcyclopropane and platinum complexes. The order of reactivity follows the series X = EtO > > Me > H, and [Pt2Cl2(μ-Cl)2(C2H4)2]> [{PtCl2(CH2CH2CH2)}4] and the rate is accelerated in polar solvents. Mechanisms in which the arylcyclopropane first coordinates to platinum and then undergoes ring opening reactions are proposed." @default.
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• W1539257349 date "1978-05-01" @default.
• W1539257349 modified "2023-09-23" @default.
• W1539257349 title "Reactions and properties of some trimethyleneplatinum(IV) complexes" @default.
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• W1539257349 doi "https://doi.org/10.1016/s0022-328x(00)84732-4" @default.
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