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- W1539468081 abstract "Open chain unsaturated alcohols1, having the general formulaR1R2C=CH(CH2)nCR1R2OH (whereR1,R2=H or CH3, andn=1–3) and carbocyclic unsaturated alcohols of similar type have been efficiently cyclized to the corresponding hydroxytetrahydrofuran or hydroxytetrahydropyran over titanium silicate molecular sieves (TS-1 and Ti-beta), in one pot under mild liquid phase reaction conditions using dilute hydrogen peroxide as oxidant. When the hydroxy nucleophile may attack either of the activated carbon atoms of the epoxides generatedin situ, to lead to a derivative of tetrahydrofuran or tetrahydropyran, the former exclusively formed. The regioselectively for such reaction is 100%. WhenR1orR2=CH3, among the diasteroisomeric productstranspredominates overcis. In this cyclization reaction titanium silicate epoxidizes the olefin and successively catalyzes the opening of the oxirane ring via intramolecular attack of hydroxy oxygen. Thus the behavior of titanium sites is bifunctional in nature. However, for bicyclic unsaturated alcohols, because of geometric restriction, activity of medium pore TS-1 is very low. Ti-beta synthesized by dry gel conversion has been found to be an efficient catalyst in oxidative cyclization of such bulky organic substrates as α-terpineol, isopulegol, andtrans-p-menth-6-ene-2,8-diol to their corresponding tetrahydrofuranols or tetrahydropyranols with a very high regioselectivity." @default.
- W1539468081 created "2016-06-24" @default.
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- W1539468081 date "1999-03-01" @default.
- W1539468081 modified "2023-10-16" @default.
- W1539468081 title "Intramolecular Rearrangement of Epoxides Generatedin Situover Titanium Silicate Molecular Sieves" @default.
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- W1539468081 doi "https://doi.org/10.1006/jcat.1998.2355" @default.
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