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- W1539976926 abstract "A series of alumina supports containing various amounts of fluorine was prepared by soaking γ-Al2O3 in solutions of ammonium fluoride to obtain supports of lowered Al-OH contents. Catalysts containing 5.8% molybdenum, prepared from these supports, were tested in their sulfide state for nitric oxide chemisorption and thiophene hydrodesulfurization (HDS) activity. A small to moderate decrease in nitric oxide adsorption and HDS activity was obtained with increasing fluorine content of the catalyst. This was interpreted in terms of lower interaction between molybdenum and Al-OH resulting in larger MoS2 slabs. Of significance was a relatively high nitric oxide adsorption and HDS activity on the high F--Al2O3 support containing no residual Al-OH. It is suggested that non-OH, active alumina sites can also interact with molybdenum to form a highly dispersed molybdenum phase on the alumina surface, and that this route can contribute significantly to the molybdenum dispersion." @default.
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- W1539976926 date "1989-04-01" @default.
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- W1539976926 title "Studies of molybdena—alumina catalysts" @default.
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- W1539976926 doi "https://doi.org/10.1016/s0166-9834(00)83021-3" @default.
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