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- W1540132380 abstract "A mechanism of ligand exchange between ferrocene and arenes catalysed by AlCl3 is presented. It is shown how the attacking sites of AlCl3 depend on the electronic effect of substituents on the ferrocene rings. In ferrocene and its alkyl derivatives, two types of complexation occur and compete with each other: complexation of a ring reversibly leads to cleavage; irreversible complexation of the metal, possible only in the absence of electron-withdrawing substituents, inhibits metal—ligand cleavage." @default.
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- W1540132380 date "1976-05-01" @default.
- W1540132380 modified "2023-09-30" @default.
- W1540132380 title "Contribution to the study of metallocenes" @default.
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- W1540132380 doi "https://doi.org/10.1016/s0022-328x(00)98142-7" @default.
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