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- W1540306607 abstract "Kinetic spectroscopy of a flash-photolyzed mixture of Xe and UF6 yielded the B-X transition (300–355 nm) of XeF in absorption. Vibrational assignments were made for 22 bands (0 ≤ v′ ≤ 12, 0 ≤ v″ ≤ 3), and were confirmed by computer modeling of the relative absorption intensities. Spectroscopic constants for XeF (B-X) are: Te = 28 813.9 ± 0.5 cm−1, ω′e = 308.23 ± 0.5 cm−1, ωeχ′e = 1.4266 ± 0.03 cm−1, ω″e = 225.06 ± 1.4 cm−1, ωeχ″e = 10.568 ± 0.4 cm−1, and ΔRe = R′e - R″e = 0.35 ± 0.02 Å. A linear Birge-Sponer extrapolation yields a ground state XeF dissociation of about 1200 cm−1." @default.
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- W1540306607 date "1978-01-01" @default.
- W1540306607 modified "2023-09-26" @default.
- W1540306607 title "Flash photolysis absorption spectroscopy of xenon fluoride" @default.
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- W1540306607 doi "https://doi.org/10.1016/0022-2852(78)90021-8" @default.
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