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- W1540496408 abstract "The solute retention mechanism in gasliquid chromatography was studied in a non-polar hydrocarbon solutemoderately polar stationary phase (polypropylene glycol 2000) system. The dependences of the retention volume of a solute and the specific surface area of column packings on the liquid loading are quantitatively interpreted on the basis of a model for the distribution of a liquid phase on a solid support. In the model, the solid support surface is assumed to be successively covered with three different types of liquid phase layers, first with a monolayer, second with a double layer and finally with a bulk liquid layer, as the liquid loading increases. The changes in the enthalpy and entropy of solution and adsorption were calculated from distribution constants for bulk solution partition and for interfacial adsorption obtained by analysis at two column temperatures." @default.
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- W1540496408 date "1985-01-01" @default.
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- W1540496408 title "Adsorption effects in gas-liquid chromatography" @default.
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